ChansonRolandV6, Main, Exploration, bibRecord, 000C54

Thiol‐Catalyzed Stereoselective Transfer Hydroamination of Olefins with N‐Aminated Dihydropyridines

Identifieur interne : 000C54 ( Main/Exploration ); précédent : 000C53; suivant : 000C55

Thiol‐Catalyzed Stereoselective Transfer Hydroamination of Olefins with N‐Aminated Dihydropyridines

Auteurs : Joyram Guin ; Roland Fröhlich ; Armido Studer [Allemagne]

Source :

Angewandte Chemie International Edition [ 1433-7851 ] ; 2008-01-11.

RBID : ISTEX:722AC806909A3F3A5BB3ED236E4C6F55A6372617

English descriptors

Entity :
- pers : A. D. Smith, A. J. Katritzky, A. P. Antonchick, A. Studer, A. Tillack, B. P. Roberts, B. T. Wolff, B. Zhao, C. A. Zezza, C. A. Zificsak, C. Azap, C. G. Hartung, C. Gaulon, C. H. Hövelmann, C. J. Douglas, C. Ko, C. Mioskowski, C. Mück-Lichtenfeld, C. R. Berry, C. Rameshkumar, Chemischen Industrie, D. A. Evans, D. Faye, D. Kasi, D. Lucet, D. P. Curran, D. W. C. MacMillan, E. D. Savory, E. Eichenberger, E. Sugiono, F. Gohier, For, G. C. Lloyd-Jones, G. Dujardin, G. Thoma, H. Du, H. J. Sanganee, H. Rodriguez-Solla, H. Trauthwein, H. Xiong, J. A. Mulder, J. B. Tuttle, J. C. Walton, J. Comput, J. Guin, J. Kemper, J. Org, J. Qin, J. Seayad, J. Streuff, J. W. Suwinski, J. W. Yang, K. Bouhadjera, K. I. Booker-Milburn, K. Muæiz, L. S. Hegedus, L. V. Jackson, L. Wei, M. B. Smith, M. Beller, M. Bolte, M. Collis, M. Eichberger, M. G. Roepel, M. J. de Nie-Sarink, M. Nieger, M. P. Sibi, M. Rueping, M. T. H. Fonseca, N. J. Turro, N. Vignola, O. R. Thiel, P. A. Baguley, P. A. Lander, P. Renaud, R. Dhal, R. Fröhlich, R. P. Hsung, S. Amrein, S. G. Bosio, S. G. Davies, S. G. Quellet, S. Grimme, S. Key, S. R. Chemler, S. Schubert, T. E. Müller, T. Le Gall, T. Lu, T. Theissmann, U. K. Pandit, V. Maisonneuve, W. Adam, W. Yuan, Y. Shi, Y. Tang, Z. F. Al-Rashid, Z. Song.
- place : Friestad, Zabawa.
Teeft :
- Angew, Chem, Chiral, Chiral enecarbamates, Enecarbamates, Equiv, Hydroamination, Hydroaminations, Major isomer, Olefin, Reagent, Room temperature, Stereoselective, Various olefin, Verlag gmbh.

Abstract

Hantzsch dihydropyridines are popular reducing reagents in organocatalysis. The N‐aminated Hantzsch dihydropyridine 1 has now been used as a novel efficient precursor for Boc‐protected carbamoyl radicals. The readily prepared reagent was employed for the radical‐transfer hydroamination of various olefins. Stereoselective hydroamination of chiral enecarbamates afforded vicinal diamines in good stereoselectivities. Boc=tert‐butyloxycarbonyl.

Url:

https://api.istex.fr/ark:/67375/WNG-6CSHZPJV-1/fulltext.pdf

DOI: 10.1002/anie.200703902

Affiliations:

Allemagne

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 001A86
to stream Istex, to step Curation: 001962
to stream Istex, to step Checkpoint: 000C01
to stream Main, to step Merge: 000C61
to stream Main, to step Curation: 000C54

Le document en format XML

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<front><div type="abstract" xml:lang="en">Hantzsch dihydropyridines are popular reducing reagents in organocatalysis. The N‐aminated Hantzsch dihydropyridine 1 has now been used as a novel efficient precursor for Boc‐protected carbamoyl radicals. The readily prepared reagent was employed for the radical‐transfer hydroamination of various olefins. Stereoselective hydroamination of chiral enecarbamates afforded vicinal diamines in good stereoselectivities. Boc=tert‐butyloxycarbonyl.</div>
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Thiol‐Catalyzed Stereoselective Transfer Hydroamination of Olefins with N‐Aminated Dihydropyridines

Thiol‐Catalyzed Stereoselective Transfer Hydroamination of Olefins with N‐Aminated Dihydropyridines

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri